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Although dimer radical ions of aromatic molecules in the liquid‐solution phase have been intensely studied, the understanding of charge‐localized dimers, in which the extra charge is localized in a single monomer unit instead of being shared between two monomer units, is still elusive. In this study, the formation of a charge‐localized dimer radical cation of 2‐ethyl‐9,10‐dimethoxyanthracene (DMA),...
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