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A very simple and efficient diastereoselective synthesis of 1,2‐disubstituted alkenes has been achieved under mild conditions. Sulfoxide stabilised N‐sulfinylimines reacted with in‐situ‐generated phosphonate carbanions to give 1,2‐disubtituted alkenes in good to excellent yields. Different aryl phosphonates reacted with a range of electronically diverse N‐sulfinylimines to give alkenes with >99:1...
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