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Bimodal polyethylene (BPE)/chitin nanocrystals (CNC) injection bars with various CNC content were prepared to explore the shish-kebab crystal structure of semi-crystalline polymer induced by bio-based nanofiller under flow field. The addition of CNC enhanced the ultimate tensile strength and Young’s modulus of the injection bars. Various characterization techniques were employed to investigate the...
We report morphology, thermal analysis and beam diffraction of polyethylene chlorine-substituted precisely on every 21st backbone carbon, after solution crystallization induced by low-dimensional carbonaceous nanofillers (carbon nanotube and graphene). Kebab-like and rod-like nanofiller-induced crystals were separately observed on the surfaces of carbon nanotube and graphene. Fast-scan differential...
Crystallization of well-defined precision polyethylene with fluorine substituent on every 21st backbone carbon (PE21F) induced by low-dimensional carbonaceous nanofillers (carbon nanotube (CNT) and reduced graphene oxide (RGO)) via solution crystallization and supercritical CO2 assisted solution crystallization were investigated. Transmission electron microscopy was used to investigate the morphology...
A new family of polyolefins containing various aryl ether units have been designed and synthesized, and their thermal properties were studied. We prepared six acyclic diene monomers di(undec-10-enyloxy)aryl ether by a two-step approach and the corresponding homopolymers and copolymers with 1,9-decadiene by ADMET. Subsequent hydrogenation gave the corresponding ethylene-co-aryl ether polymers. The...
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