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UV‐curing 3D printing technology is one of the technologies with the highest molding efficiency and accuracy in the field of 3D printing. At present, the main problems of UV‐curing 3D printing materials include the high curing shrinkage and the low toughness. In this work, free radical/cation hybrid curing system was developed, the effects of expansion monomer (DHOM, 3,9‐diethyl‐3′,9′‐dihydro‐xymethyl‐1,5,7,11‐tetraoxaspiro[5,5]undecanone)...
Ultraviolet curing three dimensional printing (3DP), as an additive manufacturing technology, possesses relatively higher forming precision and faster forming speed, However, its low mechanical properties limit its applications. In this work, the morphology and properties of epoxy acrylate matrix 3DP materials modified by MethacrylPhenyl polyhedral oligomeric silsesquioxanes (MP-POSS) at different...
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