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Cadmium telluride (CdTe) thin films of different thicknesses deposited onto titanium dioxide (TiO2) nanoparticle layer by spray pyrolysis deposition (SPD) are demonstrated as major photo-active semiconductor in photo-electrochemical solar cell configuration using iodide/triiodide (I−/I3−) redox couple as a hole transport layer. The CdTe–TiO2 heterogeneous films were characterized by X-ray photoelectron...