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Herein, we show how the spatial environment in the functional pores of covalent organic frameworks (COFs) can be manipulated in order to exert control in catalysis. The underlying mechanism of this strategy relies on the placement of linear polymers in the pore channels that are anchored with catalytic species, analogous to outer‐sphere residue cooperativity within the active sites of enzymes. This...
Kovalente organische Gerüste In ihrer Zuschrift auf S. 8762 zeigen S. Ma et al., dass die katalytische Leistungsfähigkeit von Sulfonsäuregruppen in kovalenten organischen Gerüsten durch die Einführung polymerer Lösungsmittel‐Analoga verbessert werden kann.
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