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The small Sc3N cluster has only been found in such small cages as C2n (2n=68, 78, 80, 82), whereas the large M3N (M=Y, Gd, Tb, Tm) clusters choose those larger cages C2n (2n=82–88). Herein, concrete experimental evidence is presented to establish the size effect of the internal metallic cluster on selecting the outer cage of endohedral metallofullerenes (EMFs) by using a medium‐sized metal, lutetium,...
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