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Pyridinium bromide perbromide (PyHBr 3 ) and tert-butyl nitrite (TBN) catalytic system was used for the oxidation of sulfides with air as the oxidant. Under mild conditions (at room temperature), a series of sulfide substrates have been oxidized to their corresponding sulfoxides with high conversion rate. To the best of our knowledge, for the first time, the PyHBr 3 /TBN/H 2 ...
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