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Hardly reached balance between weak intramolecular‐charge‐transfer (ICT) and small singlet‐triplet splitting energy (ΔEST) for reverse intersystem crossing (RISC) from non‐emissive triplet state to radiative singlet state impedes the realization of deep‐blue thermally activated delayed fluorescent (TADF) materials. By discarding twisted‐ICT framework for flattened molecular backbone and introducing...
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