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The potential of porphyrin‐derived metal organic covalent networks (OCN) thin films on light gas separations has been recently demonstrated. However, whether or not the central metal ion of the porphyrin plays a key role on separation performance has yet to be elucidated. Here, one metal‐free and three metal‐containing (zinc(II), manganese(III), and cobalt(II)) porphyrin‐derived OCN thin films are...
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