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An efficient approach for the synthesis of benzimidazoles has been developed through the Pd‐catalyzed amination of 2‐iodobenzimines with diaziridinone. A wide range of 2‐(hetero)aryl benzimidazloes are synthesized in good to excellent yields. The reactions likely involve C,C‐palladacycles derived from 2‐iodobenzimines as the key intermediate, and the palladacycles reacted with diaziridinone to form...
A facile and efficient approach has been developed for the synthesis of carbazoles from 2‐iodobiphenyls and diaziridinone under palladium catalysis. A wide range of carbazoles were synthesized in good to excellent yields, and indole derivatives were obtained by using styrenes as the substrate. The palladacycles obtained from 2‐iodobiphenyls acted as the key intermediate, and the reaction should proceed...
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