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Weak adhesion between anodic TiO2 nanotube arrays (TNTAs) and Ti substrate is a nonnegligible obstacle for the preparation of long TNTAs and greatly limits its practical application. The TiNxOy nanoarrays prepared from TNTAs by a high-temperature nitridation process also suffer this defect. In this work, a compact layer (~ 140nm in thickness) was introduced into the bottom of TNTAs via an additional...
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