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Nanoscale, vanadia-based, quasi-liquid films of self-selecting (equilibrium) thickness were observed on TiO 2 surfaces in six ternary oxide systems (Ti–V–X–O; X=P, Na, K, Nb, Mo or W). It is demonstrated that the film appearance and thickness could be tailored via co-doping or changing the equilibration temperature. Furthermore, the observed discontinuous changes in film thickness, hysteresis...
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