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Using erythronolactol 8 as chiral C 4 synthon, a new short synthetic pathway was developed to obtain two hydantoin 2 -deoxyribonucleoside epimer derivatives 15a and 15b.
Oligonucleotides containing an aldehydic function at any preselected position in the sequence have been prepared using post-synthetic oxidation of an alkene as the key reaction. These were efficiently coupled to a reporter molecule tethered to an oxyamino linker.
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