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A powerful and concise synthesis of directly linked porphyrin‐BODIPY hybrids has been demonstrated, which consists of condensation of directly linked meso‐pyrroyl NiII‐porphyrin with arylaldehyde, oxidation with p‐chloranil, and complexation with BF3⋅Et2O. Synthesized hybrids include porphyrin dimer 6Ni, trimers 8Ni, 9Ni, tetramer 12Ni, pentamer 16Ni, hexamer 13Ni, and nonamers 17Ni and 18Ni. The...
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