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The NMR conformational study of three asymmetric phenylindenylidene ruthenium complexes 4.1–4.3, is presented. Complete 1H and 13C assignments could be obtained for 4.1–4.3 in benzene solution from multiple 2D homonuclear and heteronuclear NMR techniques. Our NMR analysis shows that each complex exists as a 55:45 mixture of two rotational isomers in slow exchange on the NMR chemical shift timescale...
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