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The renin–angiotensin system (RAS) is central to regulation of blood pressure and electrolyte homeostasis. Angiotensin‐converting enzyme (ACE), a key protease in the RAS, has a range of substrates, including N‐acetyl‐Ser‐Asp‐Lys‐Pro (Ac‐SDKP). The peptide Ac‐SDKP is cleared almost exclusively by ACE, and specifically by the N‐domain active site of this enzyme. N‐Acetyl‐Ser‐Asp‐Lys‐Pro is a negative...
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