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The cover picture shows a new silver cluster‐assembled material of {[Ag18(StBu)10(CF3COO)2(PhPO3)(PhPO3H)4(bpy‐NH2)2]∙(PhPO3H2)}n, being prepared by a facile one‐pot method. Ag18bpy‐NH2 exhibits reversible luminescent mechanochromism between blue and cyan upon external mechanical stimulation and treatment with ethanol‐acetone. In addition, the as‐synthesized Ag18bpy‐NH2 also showed reversible luminescent...
Silver cluster‐assembled materials (SCAMs) are emerging multi‐functional materials and have attracted great attention recently. In this work, we have prepared a new SCAM of {[Ag18(StBu)10(CF3COO)2(PhPO3)(PhPO3H)4(bpy‐NH2)2]∙(PhPO3H2)}n (denoted as Ag18bpy‐NH2), by a facile one‐pot method. Ag18bpy‐NH2 adopts a chain‐like structure made of Ag18 clusters bridged by bipyridyl linkers. Ag18bpy‐NH2 exhibits...
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