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Inositol orthoesters have been developed as precursors to stereodefined hexakis polyoxygenated cyclohexanes. The objective of the study was to determine if all-trans systems could be coaxed by alkali metal ions into adopting the all-axial coordinative features. This high level coordination cannot be matched by epimers whose only option is to experience monocomplexation. Only very low levels of coordination...
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