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The reaction of neutral “half-unit” copper azido complexes, made of “half-unit ligands” resulting from a monocondensation of different diamines with an aldehyde function and of end-on azido ligands, with diverse gadolinium or sodium salts, is not straightforward. The resulting complexes are mainly homodinuclear copper complexes. Heterodinuclear Cu–Gd complexes devoid of azido bridges necessitate use...
The template effect involves two main effects, first the “kinetic template effect”, in which a metal ion is able to hold two reactive functions in a position that allows a reaction to occur, followed by the “thermodynamic template effect” that favours the formation of a thermodynamically more stable product resulting from the reaction. Through the preparation of a non symmetric Schiff base, we highlight...
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