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In article number 2005328, Yuichi Negishi and co‐workers describe recent progress in the field of thiolate (SR)‐protected metal nanoclusters in three areas: synthesis, understanding, and application. The challenges that must be overcome for further development in this field and the possibilities that SR‐protected metal NCs can contribute to solving the problems facing modern society are also discussed...
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess great potential as novel functional materials. Fundamental research on metal NCs gradually started in the 1960s, and since 2000, thiolate (SR)‐protected metal NCs have been the main metal NCs actively studied. The precise and systematic isolation of SR‐protected metal NCs has been achieved in 2005. Since then,...
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