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An N‐phenylcarbazole/triazine hybrid of 2,4,6‐tris(9‐phenyl‐9H‐carbazol‐3‐yl)‐1,3,5‐triazine (TPhCz‐Trz) is successfully synthesized using cheap raw materials via facile synthesis method with a high yield of 60.9%. Good thermal (Td, 284 °C) and morphological stability are realized due to its rigid structure and three‐dimensional steric hindrance. The high triplet energy level of 2.88 eV for the host...