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Raney nickel in refluxing 2-propanol is an effective catalytic system for cleaving C O bonds in aromatic alcohols by transfer hydrogenolysis. Deoxygenation of alcohols substituted at the α-, β-, γ-, δ-, and -positions was accomplished. The reaction appears not to be sensitive to substitution about the carbinol carbon. Aliphatic alcohols do not undergo hydrogenolysis with this system. Some dehydromethylation...
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