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Molecular orientation, molecular packing structure, and electrical properties of thermally stable phthalocyanine, tert‐butylated phthalocyanine (t‐BuPcH2) in the thin film fabricated by bar‐coating method were investigated. The XRD patterns indicated that the columns composed of t‐BuPcH2 molecules formed hexagonal structure, the axis of which was parallel to the bar‐sweep direction, and t‐BuPcH2 molecules...