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Synthesis‐oriented design led us to the discovery of a series of novel cyanine‐borondifluoride curcuminoid hybrids called Nanchang Red (NCR) dyes that overcome the intrinsic low synthetic yields of symmetrical cyanine‐difluoroboronate (BF2)‐hybridized NIR dyes. The hybridization endows NCR dyes with high molar extinction coefficients, efficient red‐to‐NIR emission, and enlarged Stokes shifts. Quantum...
Novel red‐to‐NIR fluorophores called Nanchang Red (NCR) dyes have been constructed by rational structural hybridization of cyanine and borondifluoride curcuminoid. The peculiar asymmetrical layout of the three key fragments endows these long‐wavelength dyes with ideal photophysical properties and ER self‐targeting capability. The photoluminescent mechanism, revealed by quantum chemical calculations,...
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