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Toluene dioxygenase‐catalysed cis‐dihydroxylations of substituted aniline and phenol substrates, with a Pseudomonas putida UV4 mutant strain and an Escherichia coli pCL‐4t recombinant strain, yielded identical arene cis‐dihydrodiols, which were isolated as the preferred cyclohex‐2‐en‐1‐one cis‐diol tautomers. These cis‐diol metabolites were predicted by preliminary molecular docking studies, of anilines...