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In situ high-temperature Raman and Fourier transform infrared spectra were measured for aragonite, strontianite, cerussite, and witherite at ambient pressure. The orthorhombic to trigonal phase transitions were observed by the vibrational spectra for aragonite and witherite, at the temperatures of 773 and 1150 K, respectively. The isobaric mode Grüneisen parameters (γiP), derived from this study,...
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