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γ-Na2TiO3 is a novel sodium titanate with TiO5 trigonal bipyramids, and its properties have not been well characterized either experimentally or theoretically. In this study, γ-Na2TiO3 was prepared from the reaction of NaOH and coarse TiO2 particles, and analyzed by X-ray diffraction and vibrational spectroscopy. Meanwhile, the electronic structure, vibrational spectra, and thermodynamic properties...
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