The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
The reactivity of (PNP)Ni I , where PNP=( t Bu 2 PCH 2 SiMe 2 ) 2 N, with oxidants was evaluated. Towards the nitroxyl TEMPO, a 1:1 adduct is formed which was shown to have η 2 -TEMPO bound through both N and O, with the consequence that one P of the PNP ligand is displaced, leaving the pincer ligand bidentate to Ni II . DFT calculations...
A new mode of bonding of the traditionally weak ligand N 2 O to highly reducing transition metal complexes is described based on DFT calculations for a variety of late transition metals. These η 1 -NNO can be singly bent (at the central nitrogen) or doubly bent (at both N), and thus involve a triple or double M/N bond, respectively. The ligand is therefore properly termed an N-nitrosoimide,...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.