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Eine allgemeine asymmetrische Redoxarylierung von Inamiden und Thioalkinen mit chiralen Sulfoxiden wird vorgestellt. Es handelt sich um das erste Beispiel eines allgemeinen 1,4‐Chiralitätstransfers von Schwefel zu Kohlenstoff durch [3,3]‐sigmatrope Umlagerung eines Sulfoniumintermediats. Die Reaktion liefert α‐arylierte Thioester und Amide in atomökonomischer Weise und unter milden Bedingungen. Die...
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