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An efficient and facile method for synthesis of 2‐arylpyrroles through Rh(III)‐catalyzed direct CH arylation with pyrrole derivatives and aryl boronic acids has been developed. This reaction could proceed under mild reaction conditions and afford a series of 2‐arylated products in good to excellent yields. The gram‐scale experiment has been conducted to demonstrate the synthetic potential of this...
A highly efficient Rh(III)-catalyzed direct C–H arylation of indoles with aryl boronic acids under mild conditions has been developed. The methodology features wide substrate scope and excellent functional group compatibility (34 examples, up to 99% yield). The arylated products can also be conveniently transformed into biologically active polycyclic indole derivatives.
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