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Recently, the structure-property relationships of an attractive isomeric radical 1 (Phys. Chem. Chem. Phys., 2016, 18, 29041–29044) with famous phenalenyl (PLY) was investigated. Can PLY and 1 form stable π-dimers? The single point energy scan result shows that the staggered π-dimer (2) has the lowest energy. In order to explore intermolecular charge-transfer and nonlinear optical property, two π-dimers...
Dye sensitized solar cell sensitized by organic dye C219 (Chem. Mater, 2010, 22, 1915–1925) has reached the record efficiency (η) of 10.1% with comparable short-circuit current density (J sc ) but relatively lower open-circuit photovoltage (V oc ) as compared to that of ruthenium-based cells. With the motivation of further enhancing V oc , we designed three dyes 1–3 with different...
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