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The use of heteropolyacids as a reoxidant for palladium in the direct oxidation of benzene to phenol with molecular oxygen was studied as a function of the variables involved. It was shown that the oxidation system is very effective even if a molar ratio of HOAc:H 2 O of 1:2 is used. After 4 h at 130°C the benzene conversion is 15% and the selectivity for phenol is above 70%. The quantity...
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