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The enthalpies for formation of nitric oxide (NO) upon protonation of gas-phase diazeniumdiolates were examined by combining the enthalpy for loss of two NO molecules from the ion, obtained from collision-induced dissociation (CID) threshold energy measurements, with the gas-phase acidity, ΔH acid (R 2 NH), of the corresponding amine. CID of the N-methylaniline-substituted...
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