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A set of four hybrid duplexes formed by antisense oligos, each containing one North-form (3'-endo) locked 1-(1',3'-O-anhydro-β-D-psicofuranosyl)thymine block T at different sites and a matched 15mer RNA, were subjected to the RNase H cleavage reaction, showing how the transmission of the local conformation owing to a single North-locked sugar steers the conformational changes of the four neighbouring...
The nucleobase-protected partially-deuterated 5 -O-DMTr-2 # ,2 # ,3 ,4 # ,5 ,5 - 2 H 5 -2 -deoxyribonucleoside 3 -phosphoramidite derivatives 17a,b - 20a,b, containing C2 isotopomeric mixture of deuterons and protons [∼15 atom % 2 H at C2 (R), ∼85 atom % 2 H at C2 (S),; 65 atom % 2 H at C4 (#), >97 atom % 2 H at...
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