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The α-germylated nitriles R 3 GeCH 2 CN (R=Ph, Pr i , Bu t ) and germanium amides R 3 GeNMe 2 (R=Pr i and Bu t ) have been prepared and characterized and their reactivity with Ph 3 GeH in CH 3 CN has been explored to investigate their utility for the construction of Ge–Ge bonds. In each case the phenyl and iso-propyl derivatives...
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