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The properties and reactions of hydroxymethyl and hydride complexes are surveyed with an emphasis on their aqueous chemistry; then the syntheses and reactions found for macrocyclic cobalt complexes of these ligands are presented. The hydroxymethyl–cobalt(III) complex was prepared by addition of the photogenerated CH 2 OH radical to the cobalt(II) macrocycle N-meso-CoHMD 2+ (HMD=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)...
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