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We report the synthesis of a new chiral porous coordination polymer [Zn2{(R)-5,5′-BDA}2(dabco)]n·DMF (5,5′-BDA=2,2′-dihydroxy-1,1′-binaphthalene-5,5′-dicarboxylic acid, dabco=1,4-diazabicyclo[2.2.2]octane). This compound had one-dimensional (1D) channels which were occupied by DMF molecules. The hydroxyl groups on the surface of the channels acted as DMF interactive sites. Removal of DMF from the...
The chiral zinc porphyrin dimer linked by the (S)-NMe 2 or (R)-2,2'-dimethoxy-1,1'-binaphthyl tightly binds diamines via a zinc-nitrogen coordinated ditopic interaction. In particular, the zinc porphyrin displays excellent enantioselectivity towards Lys. The D/L selectivity is determined to be 11-12 for the lysine derivatives. The achiral zinc porphyrin dimers linked by biphenyl unit exhibit...
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