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Three new trinuclear nickel (II) complexes with the general composition [Ni3L3(OH)(X)](ClO4) have been prepared in which X=Cl− (1), OCN− (2), or N3− (3) and HL is the tridentate N,N,O donor Schiff base ligand 2‐[(3‐dimethylaminopropylimino)methyl]phenol. Single‐crystal structural analyses revealed that all three complexes have a similar Ni3 core motif with three different types of bridging, namely...
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