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Poly(vinylidene fluoride) (PVDF), a polymorphic material, has useful electro active properties such as piezo‐, pyro‐, and ferroelectric properties. The piezoelectric crystallization polymorph is the β‐phase which has an all‐trans (TTTT) conformation, i.e., all of its dipoles aligned in the same direction normal to the chain axis. Elongational deformation was applied to poly(vinylidene fluoride)/multiwalled...
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