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The autoprotolysis of binary aqueous mixtures of dimethyl sulfoxide, acetonitrile, acetone, tetrahydrofuran and 1,4-dioxan is studied. It is demonstrated that except for solvent mixtures very rich in water, the autoprotolysis is produced by proton transfer from water to the dipolar organic solvent. Only in water rich mixtures the autoionization of water contributes appreciably to autoprotolysis...
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