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We characterized the acid–base properties, electrochemistry, and electrogenerated chemiluminescence (ECL) of neutral red in acetonitrile (MeCN). To determine the acid–base properties, the basic form (NR) of neutral red was prepared and titrated with anhydrous HClO 4 , yielding pK a =6.5 in MeCN. NR showed three irreversible electrochemical oxidations and a one-electron reversible reduction...
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