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A retrospective overview of electrochemical studies of semiconductor nanocrystals (NCs) is given. The electrochemical behavior of monodisperse NCs in a non-aqueous supporting electrolyte can be derived from the electron quasiparticle energy and the electron self-energy. Coulomb blockade can sometimes be observed in Si NCs if the charged NCs are stable. Many NCs, such as Ge, CdS, CdSe, PbS and core-shell...
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