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A simple and efficient method for the synthesis of ultrasmall Pd nanoclusters (NCs) has been developed. The as-obtained Pd NCs displayed uniform size with an average diameter of 1.8±0.2 nm. The ultrasmall Pd NCs and carbon nanotubes (CNTs)-supported Pd NCs also showed outstanding catalytic activity for nitrobenzene reduction and Suzuki coupling reactions. Notably, the reactions were conducted under...
A simple and efficient solution-based method for the synthesis of Pd-Ni bimetallic nanoparticles (NPs) has been developed. A series of Pd-Ni bimetallic NPs were readily achieved by reduction of PdCl2 and Ni(acac)2 (acac = acetylacetonate) in the presence of oleylamine (OAm), oleic acid (OA) and benzyl alcohol. Furthermore, by using high-resolution transmission electron microscopy (HRTEM), energy-dispersive...
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