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The precise self‐assembly of building blocks at atomic level provides the opportunity to achieve clusters with advanced catalytic properties. However, most of the current self‐assembled materials are fabricated by 1/2D assembly of blocks. High dimensional (that is, 3D) assembly is widely believed to improve the performance of cluster. Herein, the effect of 3D assembly on the activity for electrocatalytic...
Atom‐precise nanoclusters‐metal‐organic framework (APNC/MOF) composites, as bifunctional material with well‐defined structures, have attracted considerable attention in recent years. Despite the progress made to date, there is an urgent need to develop a generic and scalable approach for all APNCs. Herein, the authors present the Exploiting Fracture Strategy (EFS) and successfully construct a super‐stable...
Silver nanoclusters (NCs) are of significant interest owing to their interesting structural, electronic, and catalytic properties. Among these NCs, Ag25(SR)18 is particularly attractive due to its identical geometry as its Au counterpart, Au25(SR)18. Herein, the site‐specific electronic properties of Ag25(SR)18 and Au25(SR)18 using X‐ray spectroscopy experiments and quantum simulations are presented...
Thiolate‐protected nanoclusters with different charge states usually show similar structure frameworks but different electronic configurations, which are proved to dramatically affect their properties such as magnetism, photoluminescence, and catalytic activity. Until now, few nanoclusters with alterable charge states have been reported and only some of them are structurally solved, limiting the in‐depth...
In article number 1902703, Xi Kang and Manzhou Zhu review recent advances in studying selenol protected nanoclusters, including the synthetic methodology, the structure elucidation, and the property investigation, which provide researchers attempting to study selenolated nanoclusters with a synthetic toolbox and researching fundamentals.
The past decades have witnessed great advances in controllable synthesis, structure determination, and property investigation of metal nanoclusters. Selenolated nanoclusters, a special branch in the nanocluster family, have attracted great interest in these years. The electronegativity and atomic radius of selenium is different from sulfur, and thus the selenolated nanoclusters are anticipated to...
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