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Poly(vinylidene fluoride)/halloysite nanotubes (PVDF/HNTs) nanocomposites were prepared via melt compounding. Electroactive β- and γ-phases of PVDF were nucleated by the HNTs due to electrical interaction between negatively charged surface of the HNTs and CH 2 groups of the PVDF. The ends and surface defects of the HNTs were also responsible for the formation of γ-phase, since long trans conformations...
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