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Mucopermeating nanocargoes being able to overcome mucosal, as well as extracellular barrier leads to enhance penetration of poorly soluble anticancer drugs at its target site. We developed an innovative means to bring amphiphilic mucopermeating functional micelles to tumors. Papain (Pap) grafted thiolated hyaluronic acid‐pluronic F127‐lithocholic acid triblock (Pap‐THA‐g‐F127‐SS‐LCA) was synthesized...