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The two dissociation channels of HOOH, namely, HOOH and HOOH, in water and methanol are investigated using umbrella‐sampling ab initio molecular dynamics. Our potential of mean force calculations reveals the HOOH dissociation to be more favorable in methanol with a free energy barrier of 7.56 kcal/mol, while the HOOH dissociation possesses a free energy barrier of 11.46 kcal/mol. In water, the...
BACKGROUNDA significant share of the cost of cancer care is concentrated in the end‐of‐life period. Although quality measures of aggressive treatment may guide optimal care during this timeframe, little is known about whether these metrics affect costs of care.
METHODSThis study used population data to identify a cohort of patients who died of cancer in Ontario, Canada (2005‐2009). Individuals were...
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