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Equilibrium passive sampling methods (EPSMs) allow quantification of freely dissolved contaminant concentrations (Cfree) in sediment porewater. Polydimethylsiloxane (PDMS) is a convenient sampling polymer that can be equilibrated in field (in situ) or laboratory (ex situ) sediments to determine Cfree, providing reliable compound‐specific PDMS–water partition coefficients (KPDMS‐water) are available...
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