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This work reviews the dynamic behavior in solution of seven-coordinated complexes of different transition metals containing mono and polydentate monohapto ligands. The complexes are classified according to their geometry in the solid state, established by X-ray diffraction: pentagonal bipyramidal (PBP), capped octahedral (cO), capped trigonal prismatic (cTP), and complexes with 4:3 tetragonal base-trigonal...
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